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Electrospinning of polymeric nanofiber (nylon 6,6/graphene oxide) for removal of Cr (VI): synthesis and adsorption studies

Journal of Analytical Science and Technology volume 10, Article number: 13 (2019) | Download Citation

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Abstract

Polymer nanofibers are valuable materials that are of great importance because they are inexpensive and they display high strength. In this study, nylon-6,6 (N6,6)/graphene oxide (GO) nanofibers were developed and characterized. GO was synthesized from graphene using the known Hummer’s method. GO is obtained by reaction of the graphene with strong oxidants and was characterized using Fourier-transform infrared spectroscopy (FT-IR) and scanning electron microscopy (SEM). The characterizations showed that the graphene was suitably oxidized. GO was added to N6,6 to produce N6,6/GO nanofibers at loadings of 0.5, 1.0, 1.5, and 2.0 wt% through the melt mixing method. The batch adsorption model for Cr (VI) adsorption was applied as a function of time, initial Cr (VI) concentration, adsorbent dosage, and pH to examine nanofiber activity. N6,6/GO a exhibited high adsorption capacity for Cr (VI) at pH 2.0. The maximum adsorption capacity for Cr (VI) ion was found to be 47.17 mg/g of N6.6/GO using the related isotherm curves and equations. When the equilibrium data were examined, it was concluded that Langmuir adsorption isotherm was more suitable.

Introduction

There is a grade demand to use corrosion-resistant and solvent-resistant low-density organic materials for simple installation and industrial purposes. Recently, graphene-doped materials have been broadly used in semiconductors and nanofibers (Coiai et al. 2015). Semi-crystalline polymers contain a huge number of organic materials including crystalline and amorphous molecular structures. Polyolefin, polyester, polyamide, and vinyl are some examples of imperative groups of organic semi-crystalline polymers. It is well-known that semi-crystalline polymers are liable for the crystal phase charge transfer, that is, mechanical and non-viscous mechanical behaviors capable of applying incredible physical force depends on this phase response (Pouriayevali et al. 2013). For this reason, it is important to enter into details about the crystal phase of semi-crystalline materials used in industry. Recently, polyamides (nylon) as a group of semi-crystalline polymers joined with nanomaterials have received great interest due to their extensive applications. Nanocomposite polymers have high mechanical properties such as modulus, strength, and hardness.

In recent years, industrial wastewater harmful components have increased particularly in developing countries. For this reason, desalination of the water is one of the foremost promising chemical actions to provide clean water for dry areas. Various desalting strategies for removing dissolved solids, like reverse osmosis (Pontiéa et al. 2013) and pressure differences (Syrwade et al. 2015), membrane separation (Korus and Loska 2009), electrodialysis (Nataraj et al. 2007), reverse osmosis (Hafez and El-Manharawy 2004), chemical precipitation (Vasudevan et al. 2012), and ion exchange (Oehmen et al. 2014) are well known strategies applied for wastewater purification or remediation. The new two-dimensional graphite plates were applied as a chemically modifiable desalination material because of their extremely strong and unique physical and mechanical properties (Konatham et al. 2013). However, current strategies have disadvantages like a high operative and capital cost, restricted tolerance to the hydrogen ion concentration range of wastewater, incomplete metal removal percentage, and a huge quantity of energy demand. Hence, the adsorption techniques using modified organics are currently about to be a good, efficient, and economic methodology for harmful metal treatment method (Luo and Lü 2015). N6,6/GO offers flexibility in style, ease of use, and leading to high-quality refined wastewater. Adsorbent materials containing activated carbon (Huang et al. 2007; Gerçel et al. 2007), zeolites (Panuccio et al. 2009), chitosan (Bamgbose et al. 2010), and lignocellulose (Shin et al. 2007) were tested and developed within a previous couple of decades. However, most of those adsorbents do not seem to be effective in water purification systems and there is no effective diffusion or limitation of effective surface areas. They have caused issues like difficulty in remediation from effluents or the production of secondary wastes.

GO is obtained by treating graphite with sturdy oxidizers. the word “oxide” is inaccurate used word however traditionally established in science because graphite is not a metal. The bulk material disperses in basic solvent yielding GO. Starting from the graphite, ultrasonic agitation is the most suitable option for GO production. GO is a compound composed of organic atoms like C, O, and H at numerous ratios, typically is obtained by process graphite with sturdy oxidizers. The bulk volume of them disperses in basic medium yielding monomolecular sheets, called as GO by similarly to graphene, the single-layer form of graphite (Ma et al. 2013). GO layers have shown an increasing interest as a possible intermediate for the production of graphene in the near future (Chen et al. 2018). The termination of every layer has carboxyl and carbonyl groups. N6,6 has an excellent mechanical resistance because of hydrogen bonds and their cross-linking and the long chains being brought along for attraction (Menchaca et al. 2006).

Electrospinning is a noted technique to produce polymer fibers ranging in diameter from 40 to 2000 nm. Electrospinning starts once the electric force of the mother liquid surface exceeds the surface tension and initiates an electric spark provoking the solution to be expelled from the syringe, and a jet flows and therefore the nanofibre is collected on a metal screen. To take advantage of the properties of each material, N6,6 and GO were combined as a hybrid nanocomposite (Nirmala et al. 2015).

In this work, the selective N6,6/GO nanocomposite has been applied with success in the removal method and Cr (VI) adsorption from the aqueous solution with pH, time, and adsorbent quantity have been investigated. There are no reports on the work of N6,6/GO interaction for the Cr (VI) adsorption. N6-6 has a high mechanical resistance due to the mutual attraction of its long chains. By combining the properties of N6,6/GO, a new hybrid material was produced. This nanocomposite has some functional groups such as such as a carboxyl group (-COOH), a hydroxyl group (-OH), an amine group (-NH), and a carbonyl group (-CO) which may interact with Cr (VI) ion.

Materials and methods

Materials

N6,6 from Sigma-Aldrich and DMF from Sigma-Aldrich were purchased and all other chemicals (NaOH, HCl, formic acid, chloroform) were purchased from Merck Company. We produced GO in our laboratory. Figure 1 shows the structure of N6,6, graphene, and GO. Ultrapure water was used for preparation of Cr (VI) stock solution and other solutions. The stock Cr (VI) solution was originated by dissolving K2Cr2O7 salt (purity: ≥ 99.9%) (Merck) in pure water. For pH adjustment of solution phase, 0.1 M NaOH and HCl solutions were added in the prepared Cr (VI) solutions.

Fig. 1
figure1

Chemical structures. a N6,6. b Graphene. c GO

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N6,6/GO electrospun nanocomposite production

Glassman High Voltage Inc. brand power supply unit and AC/DC current power supply (in Fig. 2) were used to obtain 1–50 kV and 0.1–100 mA. Universal 801 syringe pump was used to receive a fixed quantity of solution from the syringe tip. Electrospinning polymer is a technique for long and continuous nanofiber production. The high voltage power supply consists of two main sections; electrospinning and a syringe pump. After preparing the polymer solution in a suitable container, it was placed inside a syringe or capillary tubing and then connected to a high voltage power supply. An electrical field was created between the grounded collector (anode) and the tip of the syringe (negative pole). The high voltage power supply is critical to provide the force of electrospinning and continuity of spinning. A syringe pump (feeders) is employed to send the polymer solution in the syringe at a selected flow rate of the polymer.

Fig. 2
figure2

Nanofiber production with electrospun method (graphene added N6,6 injection)

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Polymer drops at feeder unit hanging at the tip of the syringe were in a spherical form up to a critical voltage, due to the surface tension force applied. The applied potential difference (high electric field) reaches a threshold worth and also the surface electrostatic forces are synchronic to tension forces. Polymer drops changes to cone shapes at this time. This cone is named Taylor cone. A jet shoots through the tip of Taylor cone and follows totally different paths once it moves between the syringe needle and the collector. On the way, the solvent in the polymer solution evaporates in the air. As the polymer jets get closer to the collector, new polymer jets in nano-diameter forms and they were collected on the grounded conductive collector (Shin et al. 2001).

In this study, the solution preparation method has been started initially by solving of N6,6. As seen in Fig. 3, N6,6 solution was prepared by adding formic acid to 3 g pellets form of N6,6 and the solution was stirred continuously by a magnetic stirrer till they were mixed fully. At that point, the graphene nanoparticles (GNP) (5 wt%) have been included into 30 mL of formic acid mixed with 9 mL chloroform (Fig. 3a). We added chloroform to the formic acid solution to homogenize the solution before adding N6,6 (Fig. 3b). In that way, the particles can distribute homogeneously throughout the solution. After 10 min of mixing this solution with an ultrasonic blender, N6,6 was added and to the solution then the solution was mixed with a probe appended sonicator (50 kHz frequency) for 1 h. Heat is evolved because of working of the sonicator with sound waves. This heat causes the temperature of the solution to increase. As shown in Fig. 3c, an ice bath was placed at the bottom of the solution vessel to balance the temperature. This prepared solution was taken in 5 mL syringe to obtain nanofiber. In the experimental set-up, a supply pump was adjusted to 1 mL/s speed and the syringe tip is set to be a 12 cm distance from the drum. The high voltage power supply can set to a voltage value of 22 kV to start the nanofiber production. The nanofiber production was carried out at 25 °C in the laboratory.

Fig. 3
figure3

a Solving N6,6 in formic acid. b Distribution of GNP in chloroforms. c Preparation of N6,6/GO nanocomposite

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FT-IR studies

The FT-IR is an important analysis for the evaluation of functional groups. The FT-IR spectra of the material were recorded and given in Fig. 4. FT-IR proves the chemical structure of GO showing the metal binding chemical groups such as O-H bonds at 3310 cm−1, the stretching vibrations of -COOH bonds at 1715 cm−1, stretching vibration of C=C bonds at 1630 cm−1 (Liu et al. 2018), and -C-O stretching vibration at 1250 cm−1 (He et al. 2015). FT-IR indicated the chemical structure of the nylon 6,6, with the certain chemical groups such as N–H stretching peaks at 3299 cm−1, C–H stretching at 2861–2933 cm−1, amide-I at 1637 cm−1, amide-II at 1536 cm−1 (Haggenmueller et al. 2006), and amide-III at 1370 cm−1, O=C–H at 581 cm−1, C–C at 687 cm−1 (Charles et al. 2009). FT-IR confirmed the chemical groups related to the N6,6/GO nanocomposite such as the bands at 1638 cm−1 are assigned to C=C skeletal stretching. The broad peak at 2954 cm−1 shows the stretching vibrations of -OH bonds. The peaks at 1371 cm−1 reflect the carboxylic acid groups due to the O–H in-plane deformation and C=O stretching vibration (Shin et al. 2001; Chen et al. 2010). The O=C–H broad peak and C–C stretching peaks appeared at 592 cm−1 and 689 cm−1, respectively.

Fig. 4
figure4

Fourier-transform infrared spectroscopy (FT-IR) spectra of N6,6 nanofibers, GO, and N6,6/GO nanofibers

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SEM-EDX analysis

SEM is normally used to characterize an adsorbent by giving some knowledge about its surface topology as well as morphology and was used for determining the nanofiber size and shape. The morphology of the electrospun N6,6/GO nanofibers were randomly oriented in the SEM image (Fig. 5a). The elemental mapping of N6,6/GO nanofibers by EDX showed that carbon, nitrogen, and oxygen are the main elements of the nanofibers (Fig. 5b–d). The analysis displayed the existence of carbon (C), oxygen (O), and nitrogen (N) together with the wt% concentrations of 51.62, 26.18, and 22.18, respectively in EDX spectrum of N6,6/GO nanofibers (Fig. 5e).

Fig. 5
figure5

SEM image of N6,6/GO nanofibers (a), EDX elemental maps (b–d), and EDX spectrum (e)

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The morphology of the electrospun Cr (VI) loaded N6,6/GO nanofibers in the SEM image (Fig. 6a) and the typical EDX spectrum of Cr (VI) loaded N6,6/GO nanofibers. The elemental mapping of N6,6/GO nanofibers by EDX showed that carbon and oxygen are the main elements of the nanocomposite. In addition, Fig. 6b–f shows the elemental mapping image regarding Cr (VI) loaded N6,6/GO nanofibers including an even distribution of C, O, N, and Cr, which further validated the successful adsorption of Cr on the surface of N6,6/GO. The elemental analysis displayed the existence of carbon (C), oxygen (O), chromium (Cr), and nitrogen (N) with the wt% concentrations 35.13, 38.69, 7.44, and 18.73 respectively (Fig. 6g).

Fig. 6
figure6

SEM image of N6,6/GO nanofibers after Cr (VI) adsorption (a), EDX elemental maps (b–f), and EDX spectrum (g)

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Adsorption of Cr (VI) experiments

The Cr (VI)-adsorbent interaction was carried out as follows: the adsorption kinetics at a certain temperature was tried by adding of N6,6/GO at a dose of 0.2 g/L to a series of 10 ppm Cr (VI) solution at an initial pH of 2. The beakers were moved to the shaker (250 rpm) for different times (5 min, 15 min, 30 min, 1 h, 2 h, 4 h, 6 h, 9 h, 12 h, 18 h, and 24 h) and were maintained at 25 °C. The effect of different adsorbent dose on the adsorption of Cr (VI) from the solution phase was studied by shaking 10 ppm Cr (VI) solution with the N6,6/GO (Fig. 7).

Fig. 7
figure7

Image of Nylon 6,6/graphene oxide nanofibers before and after Cr (VI) adsorption

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N6,6/GO dosages in the solution phase were 0.05, 0.1, 0.2, 0.3, and 0.4 g/L. The different initial concentrations of Cr (VI) (2.5, 5, 7.5, 10, 12.5, 15, and 20 ppm) were studied and initial pH of the solution was adjusted to 2. The effect of initial pH on the adsorption was studied by adding 0.2 g/L N6,6/GO to a series of beakers containing 10 ppm Cr (VI) solution and initial pH was adjusted by adding 0.1 M NaOH and 0.1 M HCl solution from 2 to 6. The beakers were shaken (250 rpm) at room temperature for 5 h. After centrifugation, the residual Cr (VI) concentration in the supernatant liquid was analyzed spectrophotometrically at 540 nm using UV-visible spectrophotometer (ELICO-156) and 1,5 diphenylcarbazide (purity ≥ 98, Merck) as a complexing agent. Diphenylcarbazide reacts with Cr (VI) ions in acidic medium to form a purple Cr (III)-diphenylcarbazone complex (Altun et al. 2016). The maximum capacities of the synthesized N6,6, N6,6-G, N6,6/GO (3%), N6,6/GO (5%), and Cr (VI) ions were given in Fig. 8. N6,6/G has the lowest Cr (VI) adsorption capacity. In case of using GO instead of graphene in the composite, the situation changed. That means as GO ratio increased, Cr (VI) adsorption capacity increased. For that reason, N6,6/GO (5%) was preferred as the adsorbent in the rest of the experiments.

Fig. 8
figure8

Comparative adsorption capacity

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Results and discussion

N6,6 is a widely applied thermoplastic polymer in a composite film due to its corrosion resistance, rigidity, good stability, strong insulation, high mechanical strength, and excellent load holding capacity. In addition, the low-density property makes it lighter. Nylon-6 or polycaprolactam is synthesized by ring-opening polymerization of a cyclic amide, i.e., caprolactam. It was interesting to ascertain that nylon 6,6 could be rearranged to amidoxime functions and they have good complexing properties toward metal ions in the aqueous phase (Pantchev et al. 2007).

Effect of Cr (VI) initial concentration

Figure 9 presents the adsorption isotherms at pH 2.0 as the relationship between the amount of Cr (VI) adsorbed per unit mass of a given N6,6/GO and the equilibrium concentration of Cr (VI) ions in solution. The isotherms were obtained at a starting Cr (VI) concentration range of 2.5–20 mg/L.

Fig. 9
figure9

Adsorption isotherms of Cr (VI) adsorbed by N6,6/GO (equilibrium time: 6 h, dosage: 2 g/L, pH = 2.0, temperature: 25 °C)

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It is clear that Cr (VI) ions are better adsorbed to the N6,6/GO and the composite has an adsorption capacity of 47.17 mg/g. The Langmuir, Freundlich, Dubinin-Radushkevich, and Scatchard isotherms were used using Eqs. 1, 2, 3, and 4, respectively (Parlayıcı et al. 2015).

$$ \frac{C_e}{q_e}=\frac{1}{K_b{A}_S}+\frac{C_e}{A_S} $$
(1)
$$ \log {q}_e=\log {K}_f+\frac{1}{n}\log {C}_e $$
(2)
$$ \ln {\mathrm{q}}_{\mathrm{e}}=\ln {\mathrm{q}}_{\mathrm{m}}-{\beta \varepsilon}^2 $$
(3)
$$ {\mathrm{q}}_e/{\mathrm{C}}_e={\mathrm{Q}}_{\mathrm{s}}{\mathrm{K}}_{\mathrm{s}}-{\mathrm{q}}_{\mathrm{e}}\mathrm{Ks} $$
(4)

qmax and KL were obtained from the slope and intercept of the plot of Ce/qe versus Ce shown in Fig. 10a. The Langmuir isotherm parameters are given in Table 1. The value of the regression R2 obtained (0.999) showed the applicability of the isotherm.

Fig. 10
figure10

Isotherms plot for the adsorption of Cr (VI) onto N6,6/GO. a Langmuir. b Freundlich. c Dubinin-Radushkevich. d Scatchard

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Table 1 Equilibrium isotherm model parameters
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The essential characteristics of a Langmuir isotherm can be expressed in terms of a dimensionless constant separation factor or equilibrium parameter, RL which is defined by the following Eq. (5):

$$ {R}_L=1/\left(1+{K}_L{C}_e\right) $$
(5)

Where Ce is the initial concentration and RL indicates the shape of the isotherm (RL > 1 unfavorable; RL = 1 linear; 0 < RL < 1 favorable and RL = 0 irreversible). The RL values (0.017) obtained in this study are between 0 and 1 and shows the high affinity of N6,6/GO for Cr (VI) ions. The higher determination coefficients R2 (> 0.999) of the Langmuir equation suggest that the Langmuir equation can be used to fit the experimental adsorption data and to evaluate the maximum Cr (VI) ions adsorption capacity of the N6,6/GO. The results also show that the adsorption of Cr (VI) with N6,6/GO took place in a single-layer adsorption form. The linear form of the Freundlich isotherm equation is given in Eq. (2). The linear plot of lnqe against lnCe is shown in Fig. 10b and the constant n and Kf are calculated from the slope and intercept. The Freundlich isotherm constants are presented in Table 1. The low detection coefficients of Freundlich R2 (0.814) indicate that isotherm data do not fit the Freundlich model.

The D-R isotherm was applied with a linear plot of lnqe against ɛ2 shown in Fig. 10c. D-R isotherm parameters are given in Table 1. When the E value is lower than 8 kJ/mol, the sorption process is said to be predominant by physical adsorption. If E is between 8 and 16 kJ/mol, the process is dominated by a chemical ion exchange mechanism and by a chemical particle diffusion (Bering et al. 1972). The E value obtained in our work is 15.81 kJ/mol indicating the chemical ion exchange process between N6,6/GO and Cr (VI) ions in the solution phase.

Adsorption isotherms were analyzed and fitted using Scatchard equation (Fig. 10d). They were used to estimate and compare the saturation capacities of N6,6/GO toward the Cr (VI) ions. When Scatchard plot is originated from linearity, more emphasis is placed on the analysis of the adsorption data in the context of the Freundlich model in order to produce the adsorption isotherms of the metal ion at certain concentrations in the solutions. To form adsorption isotherms of Cr (VI) on N6,6/GO, the adsorption characteristics were analyzed from Scatchard plot. The value of the R2 regression (0.978) indicates that Langmuir model can be applied for the adsorption process. Scatchard analysis of equilibrium binding data for Cr (VI) ions on N6,6/GO led to a linear plot showing that the Langmuir model could be applied in the adsorption of Cr (VI) ions.

Many investigations have been carried out on the removal of Cr (VI) from the aqueous solution (Table 2). N6,6/GO has a higher capacity for the elimination of Cr (VI) from the solution phase compared to other adsorbents.

Table 2 Comparison of the adsorption capacities of Cr (VI) ions onto the various adsorbent
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Effect of pH

The pH value of the aqueous solution is an essential factor because it influences Cr (VI) adsorption process. pH changes the surface charge of an adsorbent and affects the ionization behavior of the adsorbent and Cr (VI) ions. The effect regarding the solution pH concerning Cr (VI) removal together with N6,6/GO is shown in Fig. 11. The removal efficiency of Cr (VI) with N6,6/GO appears to increase with pH decrease at pH range of 2.0–6.0. The maximum adsorption capacity was obtained at pH 2 and all adsorbents performed better capacity in acidic conditions than in neutral and alkaline conditions. There are various forms of Cr (VI) ion in solution, namely chromate (CrO42−), dichromate (Cr2O72−), and hydrogen chromate (HCrO4−) (Mor et al. 2007). These ionic forms depend on the pH of the solution and on the total chromate concentration. When the pH value is less than 6.8, HClO4− dominant species are stable and CrO42− are stable above pH 6.8. In the acidic medium, the protonated amine exhibits big affinity for Cr (VI) in a manner of electrostatic interaction. The increase in the pH of the solution phase caused significant weakening of the electrostatic attraction between the negatively charged Cr (VI) anions by providing a negative charge of the adsorbent surface. Thus, the adsorption efficiency is reduced. Furthermore, as the pH increases, the competition between OH− and Cr (VI) ions increases.

Fig. 11
figure11

pH effect on Cr (VI) adsorbed by N6,6/GO (equilibrium time: 6 h, dosage: 2 g/L, temperature: 25 °C)

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Effect of adsorbent dosage

An optimal adsorbent dosage should be determined to maximize the interactions between Cr (VI) ions and adsorption sites of N6,6/GO in the solution phase (Konatham et al. 2013). The relationship between N6,6/GO dosage and the adsorption capacity, as much as removal efficiency of Cr (VI), are illustrated in Fig. 12. The effect of adsorbent dosage on the Cr (VI) adsorption efficiency was investigated using different amounts of adsorbent in the range of 0.05–0.4 g L−1, and the results of the experiment showed that the adsorption process is strongly dependent on these parameters. The adsorption capacity of Cr (VI) follows with the increase of adsorbent dosage and a tendency has been observed in the adsorption process of N6,6/GO. Therefore, the adsorption capacity of N6,6/GO decreases from 1.16 to 0.25 mmol/g by increasing the adsorbent dosage between 0.05 and 0.4 g L−1.

Fig. 12
figure12

Adsorbent dosage effect on Cr (VI) adsorbed by N6,6/GO (equilibrium time: 6 h, pH: 2, temperature: 25 °C)

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A relatively slow increase in the adsorbent dosage range of 0.05–0.3 g L−1, Cr (VI) removal (R, %) from 44.32 to 89.21% was achieved. Figure 12 shows that the removal rate of Cr (VI) on N6,6/GO increased remarkably with the increase of N6,6/GO dosage from 0.05 to 2.0 g L−1, reaching nearly 90% at 0.2 g L−1. On the other hand, the adsorption capacity of Cr (VI) on N6,6/GO was considerably reduced from 1.16 to 0.7 mmol g−1 as the dosage increased from 0.05 to 0.2 g L−1. A further increase in the adsorbent dosage does not affect the values of the adsorption parameters. These results can be attributed to an increased adsorption dosage by providing more surface contact area and existing active adsorption sites, resulting in a higher removal percentage. A high dosage can cause agglomeration of the adsorbents (Zhang et al. 2011) and this situation was particularly true at a dosage of 0.2 g L−1.

Effect of contact time

Figure 13 shows the effect of contact time on the uptake of Cr (VI) by N6,6/GO. In the first 60 min, Cr (VI) was taken from the solution phase quickly. The amount of Cr (VI) adsorbed on N6,6/GO grows linearly with the increase of contact time, as it can depend on many free spaces in the surface of the adsorbent. After 60 min, the Cr (VI) adsorption increased more slowly and reached equilibrium within 240 min. Cr (VI) adsorption did not change significantly with further increase in contact time. This can be a consequence of the reduction in the available active regions of the adsorbent and the decrease in driving force (Wu et al. 2013). Based on the above results, the optimal equilibrium contact time for the following experimentation was selected as 360 min.

Fig. 13
figure13

Time effect on Cr (VI) adsorbed by N6,6/GO (pH: 2, dosage: 2 g/L, temperature: 25 °C)

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Adsorption kinetics

The pseudo-first-order and pseudo-second-order reaction equations were applied for the equilibrium system (Fig. 14). Pseudo-first-order kinetic model and pseudo-second-order kinetic model for Cr (VI) on N6,6/GO have been demonstrated in Table 3. The pseudo-second-order kinetic model was used based on the following differential equation: where k2 is the rate constant of pseudo-second-order adsorption (g mg−1 min−1). The boundary condition qt = 0 at t = 0 and the equation can be linearized as Eq. (6):

$$ \frac{1}{q_t}=\frac{1}{k_2\ {qe}^2}+\frac{1}{q_et} $$
(6)
Fig. 14
figure14

Adsorption kinetics data of Cr (VI) on N6,6/GO for different initial metal concentrations. a Pseudo-first-order. b Pseudo-second-order

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Table 3 Kinetic parameters of Cr (VI) adsorption N6,6/GO
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The pseudo-second-order kinetic model was found to agree between the experimental and calculated data, as indicated by the correlation coefficients higher than 0.99 obtained using this model.

Conclusions

N6,6/GO nanofibers were successfully fabricated through the electrospun method. GO was produced from graphene nanoparticle via conventional Hummers method. FT-IR and SEM-EDX were carried out to prove the successful oxidation of graphene nanoparticle into GO. Characterization of N6,6/GO nanofibers by FT-IR indicated the presence of GO in N6,6. The adsorption behavior of Cr (VI) onto N6,6/GO nanofibers was investigated and the adsorption was found to be dependent on pH, adsorbent dosage, initial Cr (VI) concentration, and contact time. The maximum adsorption for Cr (VI) was at pH 2.0. The equilibrium between Cr (VI) and nanofibers was reached in 360 min. The equilibrium adsorption data were correlated by four adsorption isotherm equations. Isotherm analysis demonstrated that the adsorption pattern of Cr (VI) onto nanocomposite followed the Langmuir model as well as Dubinin–Radushkevich (D–R) isotherm model. Using the Langmuir model equation, the maximum capacity of N6,6/GO was identified as 47.17 mg/g.

Abbreviations

GO:

Graphene oxide

N6,6:

Nylon-6,6

N6,6/GO:

Nylon-6,6/graphene oxide nanofibers

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Affiliations

  1. Department of Chemical Engineering, Konya Technical University, 42079, Konya, Turkey

    • Şerife Parlayıcı
    •  & Erol Pehlivan

  2. Department of Biomedical Engineering, Necmettin Erbakan University, 42079, Konya, Turkey

    • Ahmet Avcı

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Contributions

EP and AA conceived of the study and contributed in design and organization of the manuscript. AA produced GO and nylon-6,6/graphene oxide nanofibers. ŞP carried out the adsorption and kinetic experiments. ŞP and EP performed the data analysis. EP and AA did the manuscript writing and execute the data interpretation. All authors read and approved the final manuscript.

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Correspondence to Erol Pehlivan.

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Keywords

  • Graphene oxide
  • Nanocomposite
  • Adsorption
  • Chromium
  • Nylon 6,6