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Table 1 Kinetic parameters for the adsorption of selected phenolic compounds onto Fe3O4@MAA-βCD

From: Exploring the performance of magnetic methacrylic acid-functionalized β-cyclodextrin adsorbent toward selected phenolic compounds

Kinetic models

Parameters

Analytes

 

2,4-DNP

2,4-DCP

BPA

Pseudo-first-order

qe exp (mg g−1)

5.52721

4.5636

3.3980

qe cal (mg g−1)

0.2607

0.3125

0.1075

K1 (min−1)

0.0212

0.0221

0.0484

R2

0.2828

0.2445

0.0227

Δq (%)

35.2082

35.2082

36.6007

Relative error (%)

95.3213

93.1523

96.8363

Pseudo-second-order

qe cal (mg g−1)

5.5897

4.5914

3.3602

K2 (g mg−1 min−1)

0.1152

0.2602

4.2580

h (mg g−1 min−1)

11.3379

5.4855

48.0769

t1/2 (min)

0.0649

0.0567

1.2672

R2

1

0.9999

0.9999

Δq (%)

0.1194

0.2302

0.4205

Relative error (%)

0.3159

0.6092

1.1124

Elovich equation

qe cal (mg g−1)

5.5512

4.5554

3.3783

β (g mg−1)

12.2249

6.7249

18.6916

α (mg g min−1)

3.0374 × 1026

3.7480 × 1010

1.7760 × 1024

R2

0.9460

0.9573

0.7121

Δq (%)

0.1418

0.0795

0.2204

Relative error (%)

0.3751

0.1797

0.5778

Intraparticle diffusion

C (mg g−1)

5.2952

4.0993

3.2248

K (mg g min−1)

0.0286

0.0505

0.0164

R2

0.8786

0.8387

0.5114

External diffusion

Kext (min−1)

− 0.0024

− 0.002

− 0.0005

C (mg g−1)

− 1.9118

− 1.2089

− 0.9327

R2

0.7772

0.6877

0.3237

  1. The significance of the bold numbers are to highlight the correlation coefficient, R2 values obtained for each models. These values determine the selection of the model