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Table 1 Few reports related to F¯ sensing using alizarin, alizarin red S, its derivative, etc.

From: Fabrication of In(III)-alizarin red S complex trap for efficient detection of fluoride ion in aqueous environs

Sensor

Sensing method

Limit of detection (LOD) (mM)

Detection Range (mM)

References

1,2-dihydroxyanthra-quinone (alizarin)

Fluorimetric method

Trace level

0–0.084

Hirai and François (2014)

Aluminum quinalizarin complex

Spectrophotometric method

0.005

0–0.105

Barghouthi and Amereih (2017)

Al(III)-alizarin red S complex

Absorption and emission spectroscopic method

0.005

0.005–0.3

Sathish et al. (2007)

Zr(IV)-Alizarin red S complex

Absorption spectroscopic method

0.003

0.005–0.526

Cardwell et al. (1988)

Cerium-alizarin complexone

Colorimetric method

0.037–0.063

Sen et al. (1998)

La(III)-alizarin fluorine blue complex

Spectrophotometric method

0.004

0.010–0.063

Leon-Gonzalez et al. (1985)

Thorium-alizarin red S chelate

Spectrophotometric method

0–0.789

Yasuda and Lambert (1958)

La3+-alizarin complexone

Reverse phase HPLC

2 × 10–4

5 × 10–5 to 0.008

Xu et al. (2004)

Alizarin–o-aminomethylphenyl-boronic acid

Fluorescence spectroscopy

Kubo et al. (2006)

La(III)-alizarin fluorine blue S complex

Spectrophotometric method

0–0.013

Leonard and Murray (1974)

Ce(III)-alizarin complexone

Electrochemical method

9 × 10–4

8 × 10–5 to 5 × 10–3

Guanghan et al. (1991)

La-alizarin complexone

ICP-OES

6 × 10–4

0–0.003

Miyazaki and Bansho (1987)

La(III)-alizarin complexone

Voltammetric method

4.8 × 10–6 to 1 × 10–4

Jin et al. (1990)

Alizarin complexone/layered double hydroxide ultrathin film

Colorimetric method

0.012

0.003–0.024

Jia et al. (2013)