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Table 1 MS/MS conditions for the detection of target analytes by the MRM method

From: HPLC–MS/MS method for the simultaneous determination of aflatoxins in blood: toxicokinetics of aflatoxin B1 and aflatoxin M1 in rats

Analyte

Precursor ion (m/z)

Product ions (m/z)

RT (min)

CE (eV)

DP(V)

AFB1

313.1

241.1*

214.1

6.8

52

48

41

AFB2

315.1

259.3*

286.9

6.6

45

39

34

AFG1

329.1

243.0*

200.1

6.2

39

55

18

AFG2

331.0

189.0*

245.1

5.9

54

36

51

AFM1

328.9

273.1*

228.9

5.4

38

58

17

AFM2

330.9

272.9*

229.1

5.1

39

59

29

AFB1-13C17

330.0

255.1*

301.1

6.8

54

43

48

AFM1-13C17

346.2

288.2*

242.0

5.4

38

59

55

  1. *The quantifier ions
  2. RT retention time, CE collision energy, DP declustering potential