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Table 3 Typical Ca, Mg, K, and Na concentration values in a sample of Gran Sasso (GS) groundwater (column 2), theoretical values after pre-concentration without separation (column 3), Ca and Mg signals in GS groundwater (column 4), after elution procedure (column 5), after evaporation (column 7), and the relevant separation efficiencies (column 6)

From: Low-level 226Ra determination in groundwater by SF-ICP-MS: optimization of separation and pre-concentration methods

Isotope

GS (μg g−1)

GSAPCWS(x) (μg g−1)

GS (s−1)

After proc. (s−1)

Sep. eff. (%)

After evap. (s−1)

Ca

18

1000

46 · 106

0.26 · 106

99.4

10.4 · 106

Mg

9.4

500

860 · 106

1.63 · 106

99.8

65.2 · 106

Na

0.9

50

    

K

0.2

10

    

Isotope

S1

S2

S3

S4

S5

S6

Ca (μg g−1)

1

2

5

10

20

0

Mg (μg g−1)

0.25

0.5

1.25

2.5

5

0

Ra (s−1)

93(2)

93(1)

96(3)

97(1)

95(1)

85(2)

  1. In the latter part of the Ra signals with respect to increasing values of Ca and Mg, each sample was spiked at 226Ra concentration of 27.5 fg g−1