Analyte | Target Concentration | ProtoGC—Column 1 | ProtoGC—Column 2 | Conventional method | ||||
---|---|---|---|---|---|---|---|---|
Ratio (x) | ppm | Mean ± SD | 95% CI | Mean ± SD | 95% CI | Mean ± SD | 95% CI | |
Toluene | 1 | 1.12 | 1.05 ± 0.03 | 1.03–1.07 | 1.05 ± 0.03 | 1.03–1.07 | 1.05 ± 0.02 | 1.03–1.07 |
2 | 2.24 | 2.19 ± 0.04 | 2.17–2.21 | 2.20 ± 0.04 | 2.17–2.22 | 2.06 ± 0.04 | 2.02–2.10 | |
4 | 4.49 | 4.57 ± 0.14 | 4.49–4.65 | 4.62 ± 0.14 | 4.54–4.69 | 4.20 ± 0.17 | 4.02–4.38 | |
8 | 8.97 | 8.79 ± 0.16 | 8.70–8.88 | 8.55 ± 0.13 | 8.47–8.62 | 8.84 ± 0.51 | 8.30–9.38 | |
Ethylbenzene | 1 | 1.12 | 0.99 ± 0.04 | 0.97–1.01 | 0.99 ± 0.04 | 0.97–1.01 | 1.06 ± 0.03 | 1.04–1.09 |
2 | 2.24 | 2.05 ± 0.08 | 2.00–2.09 | 2.05 ± 0.08 | 2.00–2.09 | 2.16 ± 0.04 | 2.11–2.20 | |
4 | 4.49 | 4.24 ± 0.20 | 4.13–4.35 | 4.27 ± 0.20 | 4.16–4.38 | 4.45 ± 0.10 | 4.35–4.55 | |
8 | 8.97 | 7.85 ± 0.12 | 7.79–7.92 | 7.34 ± 0.12 | 7.27–7.40 | 9.21 ± 0.11 | 9.09–9.32 | |
o-xylene | 1 | 1.12 | 1.00 ± 0.03 | 0.99–1.02 | 0.97 ± 0.06 | 0.94–1.00 | 1.05 ± 0.02 | 1.03–1.07 |
2 | 2.25 | 2.15 ± 0.09 | 2.10–2.20 | 2.04 ± 0.08 | 1.99–2.09 | 2.15 ± 0.06 | 2.08–2.21 | |
4 | 4.50 | 4.13 ± 0.14 | 4.05–4.21 | 3.93 ± 0.14 | 3.85–4.01 | 4.15 ± 0.09 | 4.06–4.24 | |
8 | 8.98 | 7.96 ± 0.18 | 7.86–8.06 | 7.32 ± 0.15 | 7.24–7.40 | 8.57 ± 0.14 | 8.43–8.72 | |
m-xylene | 1 | 1.12 | 1.00 ± 0.02 | 0.98–1.01 | 1.01 ± 0.02 | 0.99–1.02 | 1.21 ± 0.02 | 1.19–1.23 |
2 | 2.23 | 2.10 ± 0.16 | 2.01–2.19 | 2.19 ± 0.12 | 2.12–2.25 | 2.55 ± 0.10 | 2.45–2.65 | |
4 | 4.49 | 4.39 ± 0.16 | 4.31–4.48 | 4.43 ± 0.12 | 4.36–4.50 | 5.10 ± 0.04 | 5.06–5.14 | |
8 | 8.97 | 7.37 ± 0.10 | 7.32–7.42 | 6.95 ± 0.08 | 6.91–6.99 | 9.89 ± 0.14 | 9.74–10.04 | |
p-xylene | 1 | 1.12 | 0.93 ± 0.02 | 0.92–0.94 | 0.95 ± 0.02 | 0.94–0.96 | 1.13 ± 0.01 | 1.12–1.15 |
2 | 2.24 | 1.9 ± 0.03 | 1.90–1.93 | 1.96 ± 0.04 | 1.94–1.98 | 2.21 ± 0.06 | 2.14–2.28 | |
4 | 4.49 | 3.95 ± 0.07 | 3.91–3.99 | 4.07 ± 0.06 | 4.04–4.11 | 4.53 ± 0.08 | 4.44–4.61 | |
8 | 8.97 | 7.21 ± 0.15 | 7.12–7.29 | 6.82 ± 0.15 | 6.74–6.91 | 9.43 ± 0.30 | 9.11–9.75 |