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Table 1 Some of the GQD-based nanocomposites for voltammetric sensors

From: Graphene quantum dot nanocomposites: electroanalytical and optical sensor technology perspective

Electrode material

GQD preparation method (precursor)

Target analyte

Electroanalytical technique

Linear range

LOD

References

BGQD/CNTsa

Hydrothermal (citric acid)

UA

Differential pulse voltammetry (DPV)

5.0 × 10−6–5.0 × 10−5 M

9.9 × 10−7 M

Wang et al. (2022)

MIP/GQDs/2D-hBN/GCE

Thermal deoxidization (graphene oxide)

SER

DPV

1.0 × 10−12–1.0 × 10−8 M

2.0 × 10−13 M

Yola and Atar (2018)

TC–GQD

Hydrothermal (espresso coffee wastes)

DA

DPV

1.0 × 10−6–5.0 × 10−4 M

2.2 × 10−7 M

Ahmadi et al. (2020)

AuNPs/GQDs/GCE

Pyrolysis (citric acid)

Norepinephrine (NE)

Square-wave stripping voltammetry

5.0 × 10−7–7.5 × 10−6 M

1.5 × 10−7 M

Fajardo et al. (2019)

GQDs@MWCNTs/GCE

Pyrolysis (glucose)

DA

DPV

2.5 × 10−7–2.5 × 10−4 M

9.5 × 10−8 M

Arumugasamy et al. (2020)

PEDOT-GQD/GCE

Electro polymerization (carbon nanofibers)

AA, DA, and UA

DPV

AA: 3.0 × 10−5–1.0 × 10−3 M

DA: 5.0 × 10−7–4.0 × 10−5 M

UA: 1.0 × 10−6–1.0 × 10−4 M

4.1 × 10−6 M

1.2 × 10−7 M

1.8 × 10−7 M

Chul Lim et al. (2022)

CuNC@ N-GQD/GCE

Hydrothermal (polyaniline)

DA, SER, and NIC

DPV

DA: 1.0 × 10−12–1.0 × 10−6 M

SER: 1.0 × 10−9–1.0 × 10−6 M

NIC: 1.0 × 10−11–1.0 × 10−6 M

1.0 × 10−12 M

1.0 × 10−9 M

1.0 × 10−11 M

Saisree et al. (2022)

Anti-cTnI/AuNPs@GQDs/SPGE

Commercial GQD from Sigma

Cardiac troponin-I

Square-wave voltammetry

1.0–1000 pg mL−1

0.10 pg mL−1

Mansuriya and Altintas (2021)

N-GQDs/PHA-L

Microwave-assisted hydrothermal (passion fruit juice)

Human breast cancer cells (MCF-7)

Linear sweep voltammetry

5–20 × 106 cells mL−1

1.0 cell mL−1

Tran et al. (2022)

Anti-AXL-fGQDs/SPCE

Pyrolysis (citric acid)

AXL receptor tyrosine kinase

DPV

1.7 pg mL−1–1.0 ng mL−1

0.5 pg mL−1

Mollarasouli et al. (2018)

GQD-SPE/aptamer

Pyrolysis (citric acid)

p24-HIV

Cyclic voltammetry

0.93 ng mL−1–93 µg mL−1

51.0 pg mL−1

Gogola et al. (2021)

  1. aBGQD boron-doped graphene quantum dots, CNTs carbon nanotubes, TC titania–ceria, AuNPs gold nanoparticles, MWCNTs multiwalled carbon nanotubes, PEDOT poly(3,4-ethylene dioxythiophene), CuNC copper nanocluster, N-GQD nitrogen-doped graphene quantum dots, GCE glassy carbon electrode, MIP molecularly imprinted polymer, Anti-cTnI anti-cardiac troponin-I, SPGE screen-printed gold electrode, PHA-L phytohemagglutinin-L, Anti-AXL anti-receptor tyrosine kinase, fGQDs amine-functionalized graphene quantum dots, SPCE screen-printed carbon electrode